2inch SiC ingot Dia50.8mmx10mmt 4H-N monocrystal
SiC Crystal Kukula Technology
Makhalidwe a SiC amachititsa kuti zikhale zovuta kukula makhiristo amodzi. Izi makamaka chifukwa chakuti palibe gawo lamadzimadzi lokhala ndi chiŵerengero cha stoichiometric cha Si : C = 1: 1 pa kuthamanga kwa mlengalenga, ndipo sizingatheke kukula SiC ndi njira zokulirapo, monga njira yojambula mwachindunji ndi njira yakugwa ya crucible, yomwe ndiyo maziko amakampani a semiconductor. Theoretically, yankho ndi stoichiometric chiŵerengero cha Si : C = 1: 1 angapezeke kokha pamene kuthamanga ndi wamkulu kuposa 10E5atm ndi kutentha ndi apamwamba kuposa 3200 ℃. Pakalipano, njira zodziwika bwino zimaphatikizapo njira ya PVT, njira yamadzimadzi, ndi njira yopangira mankhwala owonjezera kutentha kwa nthunzi.
Zowotcha za SiC ndi makhiristo omwe timapereka amakula makamaka ndi kayendedwe ka nthunzi (PVT), ndipo zotsatirazi ndizofotokozera mwachidule za PVT:
Physical vapor transport (PVT) njira inachokera ku njira ya gasi-gawo sublimation yomwe Lely anayambitsa mu 1955, momwe ufa wa SiC umayikidwa mu chubu cha graphite ndikutenthedwa ndi kutentha kwakukulu kuti ufa wa SiC uwole ndikuwonongeka, kenako graphite. chubu ndi utakhazikika pansi, ndi zovunda gasi-gawo zigawo zikuluzikulu za ufa SiC waikamo ndi crystallized monga SiC makhiristo m'madera ozungulira chubu graphite. Ngakhale njira iyi ndi yovuta kupeza makhiristo akuluakulu a SiC amodzi komanso njira yoyikamo mkati mwa chubu ya graphite ndizovuta kuwongolera, imapereka malingaliro kwa ofufuza otsatira.
YM Tairov et al. ku Russia adayambitsa lingaliro la kristalo wa mbewu pamaziko awa, omwe adathetsa vuto la mawonekedwe osasinthika a kristalo ndi malo a nucleation a makristasi a SiC. Ofufuza omwe adatsatira adapitilizabe kuchita bwino ndipo pamapeto pake adapanga njira yosinthira mpweya (PVT) yomwe imagwiritsidwa ntchito masiku ano.
Monga njira yoyambilira yakukula kwa makristalo a SiC, PVT pakadali pano ndiyo njira yokulirapo ya makristalo a SiC. Poyerekeza ndi njira zina, njirayi ili ndi zofunikira zochepa pazida zokulirapo, njira yosavuta yakukula, kuwongolera mwamphamvu, chitukuko chambiri ndi kafukufuku, ndipo yapangidwa kale mafakitale.